CH2Cl2 Molecular Geometry

Drawing and predicting the CH2Cl2 molecular geometry is very easy by following the given method. Here in this post, we described step by step to construct CH2Cl2 molecular geometry.

Key Points To Consider When drawing The CH2Cl2 Molecular Geometry

A three-step approach for drawing the CH2Cl2 molecular can be used. The first step is to sketch the molecular geometry of the CH2Cl2 molecule, to calculate the lone pairs of the electron in the central carbon atom; the second step is to calculate the CH2Cl2 hybridization, and the third step is to give perfect notation for the CH2Cl2 molecular geometry.

The CH2Cl2 molecular geometry is a diagram that illustrates the number of valence electrons and bond electron pairs in the CH2Cl2 molecule in a specific geometric manner. The geometry of the CH2Cl2 molecule can then be predicted using the Valence Shell Electron Pair Repulsion Theory (VSEPR Theory) and molecular hybridization theory, which states that molecules will choose the CH2Cl2 geometrical shape in which the electrons have from one another in the specific molecular structure.

Finally, you must add their bond polarities characteristics to compute the strength of the C-Cl bond (dipole moment properties of the CH2Cl2 molecular geometry). The carbon-chlorine bonds in the dichloromethane molecule(CH2Cl2), for example, are polarised toward the more electronegative value chlorine atom, and because all (C-H and C-Cl) bonds have the same size and polarity, their sum is non zero due to the CH2Cl2 molecule’s bond dipole moment, and the CH2Cl2 molecule is classified as a polar molecule.

The molecule of dichloromethane (with tetrahedral shape CH2Cl2 molecular geometry) is tilted at  109.5 degrees. It has a difference in electronegativity values between chlorine and carbon atoms, with chlorine’s pull the electron cloud being greater than carbon’s. As a result, it has a permanent dipole moment in its molecular structure. The CH2Cl2 molecule has a dipole moment due to an unequal charge distribution of negative and positive charges.

CH2Cl2 Molecular Geometry

Overview: CH2Cl2 electron and molecular geometry

According to the VSEPR theory, CH2Cl2 possesses tetrahedral molecular geometry and CH4-like electron geometry. Because the center atom, carbon, has two C-H and C-Cl bonds with the hydrogen and chlorine atoms surrounding it. The H-C-Cl bond generates 109.5 degrees in the tetrahedral molecular geometry. The CH2Cl2 molecule has a tetrahedral geometry shape because it contains two chlorine and two hydrogen atoms.

There are two C-H and two C-Cl bonds at the CH2Cl2 molecular geometry. After linking the two hydrogens and two chlorine atoms in the tetrahedral form, it maintains the tetrahedral-like structure. In the CH2Cl2 molecular geometry, the C-Cl and C-H bonds have stayed in the four terminals of the tetrahedral molecule.

The center carbon atom of CH2Cl2 has no lone pair of electrons, resulting in tetrahedral electron geometry. However, the molecular geometry of CH2Cl2 looks like a tetrahedral and no lone pair out of the plane. It’s the CH2Cl2 molecule’s asymmetrical geometry. As a result, the CH2Cl2 molecule is polar.

How to find CH2Cl2 hybridization and molecular geometry

Calculating lone pairs of electron on carbon in the CH2Cl2 molecular geometry:

1.Determine the number of lone pairs on the core be an atom of the CH2Cl2 Lewis structure. Because the lone pairs on carbon are mostly responsible for the CH2Cl2 molecule geometry distortion, we need to calculate out how many there are on the central carbon atom of the Lewis structure.

Use the formula below to find the lone pair on the carbon atom of the CH2Cl2 molecule.

L.P(C) = V.E(C) – N.A(C-H and C-Cl)/2

Lone pair on the central carbon atom = L.P(C)

The core central carbon atom’s valence electron = V.E(C)

Number of C-H and C-Cl bonds = N.A (C-H and C-Cl)

calculation for carbon atom lone pair in CH2Cl2 molecule

For instance of CH2Cl2, the central atom, carbon, has four electrons in its outermost valence shell, two C-H, and two C-Cl bond connections.

As a result of this, L.P(C) = (4 –4)/2=0

In the CH2Cl2 electron geometry structure, the lone pair on the central carbon atom is zero. It means there is no lone pair in the core carbon atom. These lone pair on the central carbon atom is responsible for the CH2Cl2 molecular geometry distortion.

If you imagine, there is no lone pair on the carbon atom of the CH2Cl2 molecule. Then, no electronic repulsion of C-Cl and C-H bonds pair in the CH2Cl2. That gives stable tetrahedral geometry.

But in reality, the CH2Cl2 molecule undergoes distortion in its geometry due to the polarity of two chlorine atoms in the tetrahedral geometry. This leads to tetrahedral geometry for the CH2Cl2 molecule.

Calculate the number of molecular hybridizations of CH2Cl2 molecule

What is CH2Cl2 hybrizidation? This is a very fundamental question in the field of molecular chemistry. All the molecules made by atoms. In chemistry, atoms are the fundamental particles. There are four different types of orbitals in chemistry. They are named as s, p, d, and f orbitals.

The entire periodic table arrangement are based on these orbital theory. Atoms in the periodic table are classified as follows:

s- block elements

p- block elements

d-block elements

f-block elements

Atoms are classified in the periodic table

CH2Cl2 molecule is made of one carbon, two hydrogens, and two chlorine atoms. The chlorine and carbon atoms have s and p orbital. hydrogen comes as the first element in the periodic table. The hydrogen atom has s orbital.

When these atoms combine to form the CH2Cl2 molecule, its orbitals mixed and form unique molecular orbitals due to hybridization.

How do you find the CH2Cl2 molecule’s hybridization? We must now determine the molecular hybridization number of CH2Cl2.

The formula of CH2Cl2 molecular hybridization is as follows:

No. Hyb of CH2Cl2= N.A(C-H and C-Cl bonds) + L.P(C)

No. Hy of CH2Cl2= the number of hybridizations of CH2Cl2

Number of C-H and C-Cl bonds = N.A (C-Cl and C-H bonds)

Lone pair on the central carbon atom = L.P(C)

Calculation for hybridization number for CH2Cl2 molecule

In the CH2Cl2 molecule, carbon is a core atom with two chlorine and two hydrogen atoms connected to it and no lone pair. The number of CH2Cl2 hybridizations (No. Hyb of CH2Cl2) can then be estimated using the formula below.

No. Hyb of CH2Cl2= 4+0 =4

The CH2Cl2 molecule hybridization is four. The sp3 hybridization is formed when one S orbital and three p orbital join together to form a molecular orbital.

Molecular Geometry Notation for CH2Cl2 Molecule :

Determine the form of CH2Cl2 molecular geometry using VSEPR theory. The AXN technique is commonly used when the VSEPR theory is used to calculate the shape of the CH2Cl2 molecule.

The AXN notation of CH2Cl2 molecule is as follows:

The center carbon atom in the CH2Cl2 molecule is denoted by the letter A.

The bound pairs (C-H and C-Cl) of electrons to the core carbon atom are represented by X.

The lone pairs of electrons on the center carbon atom are denoted by the letter N.

Notation for CH2Cl2 molecular geometry

We know that carbon is the core atom, with four electron pairs bound (two C-H and two C-Cl) and no lone pair. The general molecular geometry formula for CH2Cl2 is AX4.

According to the VSEPR theory, if the CH2Cl2 molecule has an AX4 generic formula, the molecular geometry and electron geometry will both be tetrahedral forms.

Name of MoleculeDichloromethane
Chemical molecular formulaCH2Cl2
Molecular geometry of CH2Cl2Tetrahedral
Electron geometry of CH2Cl2Tetrahedral
Hybridization of CH2Cl2sp3
Bond angle (H-C-Cl)109.5º degree
Total Valence electron for CH2Cl220
The formal charge of CH2Cl2 on carbon0


In this post, we discussed the method to construct CH2Cl2 molecular geometry, the method to find the lone pairs of electrons in the central carbon atom, CH2Cl2 hybridization, and CH2Cl2 molecular notation. Need to remember that, if you follow the above-said method, you can construct the CH2Cl2 molecular structure very easily.

What is CH2Cl2 Molecular geometry?

CH2Cl2 Molecular geometry is electronic structural representation of molecule.

What is the molecular notation for CH2Cl2 molecule?

CH2Cl2 molecular notation is AX4.

The polarity of the molecules

Polarity of the molecules are listed as follows

Lewis Structure and Molecular Geometry

Lewis structure and molecular geometry of molecules are listed below

External Reference:

Information on CH2Cl2 molecule

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